聚丙烯酸与铝配合物鞣剂的合成与结构表征

以聚丙烯酸和氯化铝为原料，采用溶液聚合法合成出丙烯酸树脂，再与铝离子配合，生成了一种配合物鞣剂，采用化学分析、红外光谱、差热分析、紫外光谱对产物进行了表征，结果表明该鞣剂是聚丙烯酸与铝的配合物，而不是聚丙烯酸与氯化铝的混合物。     

不同结构的树脂复鞣剂在皮革中形态的电镜研究

借助扫描电镜(SEM)观察了SCC丙烯酸皮革填充树脂、ART丙烯酸树脂复鞣剂、HMP多功能皮革材料以及RTM三聚氰胺树脂复鞣剂等4种高分子材料在皮革中的微观结构，讨论了每种材料赋予皮革的不同性能，为制革工作者在制革时正确选择皮化材料提供参考。     

Compomer的摩擦磨损特性

采用Compoglass，F2000，Elan，Dyract AP4种牙科用复合体材料(Compomer)，对其玻璃颗粒含量和表面硬度进行了测量，并在球一盘往复摩擦磨损试验机上考察了它们的摩擦磨损特性。结果表明：F2000的摩擦系数最高，Elan的摩擦系数次之，Compoglass和DyractAP的摩擦系数分别为第三和第四．摩擦系数随玻璃颗粒含量的增加而增加．在同样试验条件下，低摩擦系数的DyractAP和Compoglass与高摩擦系数的F2000和Elan相比具有较好的耐磨性．磨损机理主要表现为由玻璃颗粒脆性断裂引起的玻璃颗粒脱落和磨粒磨损。     

纳米等离子处理对提高牙科合金金瓷结合性的研究

为提高烤瓷材料与牙科合金之间的结合强度，采用Ar^ 离子轰击溅射清洁表面处理和等离子体刻蚀活化处理，并在牙科合金表面沉积纳米Al2O3膜，进行纳米表面处理。结果表明，通过处理的牙科合金与烤瓷的结合强度有所提高，当Al2O3膜厚约为1000nm时，抗折强度达到最大，为47．68MPa．与传统方法相比提高近70％，纳米膜的适宜厚度在700～1200nm之间。     

Monitoring Moisture Uptake and Delamination in CFRP-Reinforced Concrete Structures with Electrochemical Impedance Sensors

Electrochemical impedance spectroscopy (EIS) sensors have been used to inspect carbon fiber reinforced polymer (CFRP) -reinforced concrete structures exposed to a variety of test conditions. Similar specimens were also used to investigate the detection of delamination between the CFRP and the concrete using a modified wedge test configuration. The use of external electrodes attached to the CFRP surface, coupled with the embedded rebar, provided the best results. Equivalent circuit modeling was used to analyze the impedance spectra. Several circuit parameters, especially the capacitance and constant phase element (CPE) magnitude, correlated very well with both bonded area/delamination and moisture. Both parameters exhibit a linear relationship with delamination area. The capacitance also showed a linear relationship with moisture content while the CPE was more strongly dependent on moisture. Differences in the response of the specimens subjected to the different exposure conditions were seen and explained based on the moisture uptake of the various specimens.     

The Study of Low Surface Energy Fluorocarbon Coatings with Fluor Content Being Lower

A kind of low surface energy fluorocarbon coatings from the synthesized fluoro-acrylic resin was developed.The molecule orientation principle of nonpolar and polar functional groups in the coatings was analyzed. The contact angles of pure water drops on the surfaces of various fluoro-monomer homopolymers and interpolymers were measured. The relation of coatings' fluoro-content with the surface energy was determined. The distribution of fluoric functional groups in the coatings was investigated. The test results show that though the total content of fluor of the fluorocarbon coatings is relative few, their surface energy is really low due to the enrichment of fluoro-chains on the surfaces.     

Adsorption Behaviors and Mechanism of Macroporous Phosphonic Acid Resin for Gadolinium

The adsorption behaviors and mechanism of a novel chelate resin, macroporous phosphonic acid resin(PAR)for Gd(Ⅲ)were investigated. The statically and dynamically saturated adsorption capacity is respectively 308 mg·g-1resin and 296 mg·g-1resin at 298 K in Hac-NaAc medium at pH 5.6. Gd(Ⅲ)adsorbed on PAR can be reductively eluted by 0.5～5.0 mol·L-1 HCl used as eluant and the elution percentage is up to 94.7% in 1.0 mol·L-1 HCl. The resin can be regenerated and reused without apparent decrease in adsorption capacity. The apparent adsorption rate constant is k298=3.96×10-5 s-1. The adsorption behavior of PAR for Gd(Ⅲ) conforms to the Freundlich isotherm. The thermodynamic adsorption parameter, enthalpy change △H of PAR for Gd(Ⅲ)is 22.6kJ·mol-1. The apparent adsorption activation energy(Ea)of PAR for Gd(Ⅲ)is 5.0 kJ·mol-1. The molar coordination ratio of the functional group of PAR to Gd(Ⅲ)is about 3∶1. The adsorption mechanism of PAR for Gd(Ⅲ)was examined by using chemical method and IR spectrometry.     

In vivo remineralization of acid-etched enamel in non-brushing areas as influenced by fluoridated orthodontic adhesive and toothpaste

This study aimed to evaluate the in vivo remineralization of acid-etched enamel in non-brushing areas as influenced by fluoridated orthodontic adhesive and toothpaste. One hundred and twenty teeth from 30 volunteers were selected. The teeth were assigned to four treatments: no treatment (negative control); 37% phosphoric acid-etching (PAE) (positive control); PAE + resin-modified glass ionomer cement (RMGIC); and, PAE + composite resin. Patients brushed teeth with fluoridated (n = 15) or non-fluoridated (n = 15) toothpastes, so that etched enamel was protected with screens and it was not in contact with the brush bristles. Remineralization was evaluated by means of laser fluorescence (LF), environmental scanning electronic microscopy, and energy dispersive spectrometry after extraction. The LF means were compared by means of Wilcoxon and Mann Whitney tests. Environmental scanning electron microscopy scores were compared among the groups using a Kruskal Wallis test, whereas the Ca/P ratio was evaluated by means of an Analysis of Variance with subparcels (treatments) and Tukey's post-hoc test. There were no statistically significant differences between the tooth pastes and between the orthodontic adhesives evaluated. Most teeth presented only partial enamel remineralization. Therefore, the fluoride released by the RMGIC was not enough to cause increased crystal regrowth in the acid-etched enamel. The use of fluoridated toothpaste did not provide positive additional effect.     

嵌入式Linux下USB主控制器驱动的研究

介绍了USB协议分层结构,通讯原理和主机控制器驱动程序的结构,并以S1811作为实例详细分析了主机控制器驱动程序的设计和实现过程。     

分形理论在摩擦学研究中的应用

对近年国内外分形理论在摩擦学研究中应用的新进展作了综述,介绍了分形的概念以及分形维数的计算方法,讨论了包括磨损表面形貌分析,材料表界面分形研究和磨合磨损分形模型的建立等分形理论在摩擦学研究中的应用状况,并提出了当前相关研究中所遇到的问题,及今后分形理论在摩擦学研究中的发展方向。